• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    As new industrial products, the esters of the following general formula (A) <IMAGE> (A) in which R1 is alkyl radical selected from the group consisting of methyl and ethyl; R2 is an alkyl radical selected from the group consisting of methyl and ethyl; and R3 is an alkyl radical having the formula CnH2n+1 wherein n is a number from 5 to 11. Process for the preparation of said esters as well as their use in the field of lubrication, of hydraulic fluids, of oily emulsions and of thermal fluids.
    公开号:SU1264837A3
    申请号:SU802981755
    申请日:1980-09-10
    公开日:1986-10-15
    发明作者:Паоло Росси Пьер；Анастасио Мауризио
    申请人:Сниа Вискоза Сочиета Национале Индустриа Аппликациони Вискоза С.П.А. (Фирма)；
    IPC主号:
    专利说明:

    The invention relates to organic chemistry, specifically to a method for producing new mixtures of esters of polyatomic alcohols with lubricant properties. The purpose of the invention is to improve the quality of lubricants (diminution of viscosity and engine combustion smoke). Example 1. Load 0.95 to trimethylolpropane, 0.1 kg of occlohexane, 1.8 kg of hexahydrobenzoic acid, 1.4 kg of lauric acid in a 6-liter glassy four-necked reactor equipped with a stirrer, a thermometer with a long leg, and a glass column having a distillation compound, a thermometer and a cooler connected to a horizontal delaminator, in which means are provided for returning the light phase (cyclohexane) to the reactor and collecting the heavy phase (water at the bottom. The mixture is heated to 195 ° C. At the same time, water and cyclohexane are distilled off. For the first 6 hours with 67% of the theoretical amount of water is consumed. Most of the cyclohexane (0.3k is added again to the mixture during the reaction to maintain the temperature at the indicated level. The reaction is completed after about 30 hours, after which the reaction mixture is cooled to 120 ° C and added 9 3 g of alumina. The solvent is then removed by distillation under reduced pressure, yielding 3.7 kg of ester. The kinematic viscosity of the product is at 99, 38, O -28 ° C, respectively, 10.3; 91.4; 1000; 2900 cSt The residual total acidity of the product corresponds to 0.28 mg KOH / g of product. The hardening temperature of the product is -38 ° C. Example. 2. A three-necked glass liter reactor with a capacity of 3 liters is loaded with 0.27 kg of trimethylolpropane, 0.32 kg of pelargonic acid and 0.51 kg of hexahydrobenzoic acid. The reactor is equipped with a stirrer, a thermometer with a long leg, a glass column for stripping with a thermometer and a refrigerator connected to a horizontal distributor, which is equipped with means of returning the light phase (cyclohexane) to the reactor and collecting the heavy phase (water) at the bottom. A mixture of 72 heat up to 210 ° ё. After 3 hours of reaction, 70% of the theoretical amount of water is collected. At this point, 0.14 kg of cyclohexane is added to remove residual reaction water, and the organic solvent is recycled. The reaction is complete after 18 h, after which the reaction mass is cooled to 1-20 ° C ii. 1.6 g of alumina is added. The solvent is then removed by distillation under reduced pressure, and 0.925 g of ester is collected. The kinematic viscosity at 100, 25, o is, respectively, 70, 300, 600, 2200 cSt. Total residual acidity Complies with 0.19mg KOH / g of product. Example 3. A mixture consisting of 268.3 g of trimethylol propane, 801.2 g of lauric acid and 256.0 g of hexahydrobenzoic acid in a 1: 2: 1 ratio was introduced into the reaction using the apparatus and method of example 1, As a result, 1211 g of the identified product are obtained. Example 4. A mixture consisting of: 2-ethylhexyl alcohol 2; neopentyl glycol 1; 1,12-decanedicarboxylic acid 1; hexahydrubenzoic acid 4, using the apparatus and procedure of Example 1, result in a stericized product useful as a base dp lubricant, PIME 5-14. In examples 5-14, other esters are prepared by methods similar to those described for the preparation of esters Examples Tables 1 and 2 show the reagents, weight ratios and characteristics of the resulting esters, respectively. In Table 1, the following abbreviations are accepted: HB — hexahydrobenzoic acid; EGC - 2-ethylhexanoic acid; CL - lauric acid; KS stearic acid; DPG - dipropylene glycol; PE - pentaerythritol; TS Trimethylolpropane; NPG - neopentyl glycol; PEG - polyethylene glycol 400. Example 15. 0.134 kg of trimethylolpropane (84% titer), 1.981 kg of hexahydrobenzoic acid (97.9% titer), 1.265 kg of lauric acid (95% titer), 0.937 kg of neopentylglycol (titer 94%) and 0.090 kg toluene is loaded into a 6-liter four-necked glass reactor equipped with a mechanical stirrer, a thermometer, a cooler connected to the reactor, and a vapor tube connected to the cooler and to a decanter to return the light phase (toluene) to the reactor and the draining phase ( water). All this is fueled with nitrogen and heated. At 140 ° C, water and toluene start to be distilled off. Toluene is continuously recycled to the reactor with a decanter, and water is removed. During the reaction, the temperature of the reaction mixture is gradually increased from 140 to 204 ° C. The duration of the reaction is 22-24 hours. During this period of time, the release of water is, kg: According to the state at the end of the reaction, the acidity of the resulting ester is 15.3 mg KOH per 1 g sample. Next, toluene is extracted from the reaction product by purging with nitrogen at 200 ° C. The entire reaction product is then transferred to a distillation system to eliminate residual acidity. This operation is carried out in the presence of NJ with a residual Ummrt.s pressure and an evaporator temperature of 220 ° C. The balance of this operation: loading 3.9 kg (distillation head distillation 0.6 kg, ester 3.3 kg). The acidity of the ester obtained was 15.3 mg KOH / 1 g of product, and the residual content was 0.09 mg KOH / 1 g. Viscosity at 100, 40, 4.57; 23.25; 199.2 cSt The solidification temperature is 22.5 ° C. Example 16. 1.577 kg of trimethylolpropane (titer 97.7%), 2.990 kg of hexahydrobenzoic acid (titer 99%), 2.425 kg of lauric acid (titer 95%) and 0.061 kg of toluene are loaded into the apparatus described in Example 15, and the reaction is carried out under the same conditions as in Example 15. The reaction time is 36 hours. Over this period of time, the release of the reaction water is, kg: As of the end of the reaction, the acidity of the resulting ester is 17.4 mg KOH per 1 g. The toluene is removed from the reaction product according to the procedure of Example 15. The reaction product is then transferred to a distillate. system to eliminate residual acidity. This operation is carried out in the presence of N at a residual pressure of 10 mm Hg. and evaporator temperature. The balance of this operation: loading 6.4 kg (0.6 kg distillation head distillates, 5.8 kg complex sir. The resulting product acidity is 17.4 mg KOH per 1 g, the residual acidity is 0.02 mg KOH per 1 g. The bone at 100, 38, respectively, 12.0; 93.1; 1000 cSt. The temperature of solidification. The resulting lubricants have a lower viscosity (less than 10 cSt at 100 ° C), low volatility. compared with the known lubricant smoke formation.
    Table 1
    1264837
    eight,
    Continuation of table 2
     Known synthetic ester based lubricating oil
    权利要求:
    Claims (2)
    [1]
    METHOD FOR PRODUCING LUBRICANTS by reacting organic acids with alcohols when heated in the presence of an iazotropic form of a solvent, characterized in that, in order to improve the quality of the target product, hexahydrobenzoic acid or hexahydrobenzoic and stearic acid and / or lauric acid and / or lauric acid are used , and / or 2-ethylhexane, and / or 1,10-decanedicarboxylic acid, and as an alcohol, one or two, or three alcohols from the group dipropylene glycol, neopentyl glycol, polyethylene glycol-400, trimethylolpropane, pentaerythritol, 2-ethylhexyl alcohol and the process is carried out at a molar 'ratio of alcohol or mixture of alcohols and acid or mixture of acids 1: (1-4), respectively, in the presence of cyclohexane as an azeotropically forming compound at 195-210 ° C in during 18-30 h * followed by a decrease in the residual acidity of the target product by distillation of overheads or the addition of alumina in an amount of 0.015-0.20 May L.
    Priority by signs:
    09/10/79. Alcohols: trimethylolpropane, neopentyl glycol, polyethylene glycol400, pentaerythritol; acids: stearic * lauric; the ratio of alcohol and acid 1: (1-4), the azeotropic compound is cyclohexane.
    06/24/80. Alcohols: dipropylene glycol,
    [2]
    2-ethylhexyl alcohol or a mixture of alcohols; acids: hexahndrobenzoic, pelargonic, 2-ethylhexanoic, 1> 10-decanedicarboxylic, temperature 195-210 ° С.
    SU 1Я1 1264837 AZ
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    同族专利:
    公开号 | 公开日
    US4491528A|1985-01-01|
    CA1132602A|1982-09-28|
    GR69979B|1982-07-22|
    ES494878A0|1981-10-01|
    FR2478081B1|1987-09-04|
    GB2060624B|1984-07-25|
    NL8005073A|1981-03-12|
    ES8107151A1|1981-10-01|
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    DE3033694A1|1981-03-26|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    CA716087A|1965-08-17|J. R. Geigy A.-G.|Organic esters and lubricants consisting of or containing them|
    US2766266A|1950-03-27|1956-10-09|Monsanto Chemicals|Substituted 1, 5-pentanediol esters|
    GB827656A|1955-03-02|1960-02-10|Eastman Kodak Co|Improvements in synthetic lubricants|
    DE1264658B|1964-12-24|1968-03-28|Basf Ag|Synthetic lubricants|
    US4144183A|1973-01-22|1979-03-13|Henkel Kommanditgesellschaft Auf Aktien|Mixed branched and straight chain ester oils|
    DE2713440A1|1977-03-26|1978-09-28|Bayer Ag|CARBONIC ACID ESTERS, THEIR PRODUCTION AND USE AS BASIC LUBRICANTS|
    DE2758780A1|1977-12-29|1979-07-12|Bayer Ag|PENTAERYTHRITE CARBON ACID ESTER|
    DE2909517A1|1979-03-10|1980-09-18|Bayer Ag|METAL WORKING LUBRICANTS|
    JPS5656A|1979-06-15|1981-01-06|Nec Corp|Magnetic tape unit|DE3247426A1|1982-12-22|1984-06-28|Merck Patent Gmbh, 6100 Darmstadt|CUTTING OIL FOR THE BARBING PROCESSING OF COLORED METALS|
    US5164122A|1988-04-18|1992-11-17|The Lubrizol Corporation|Thermal oxidatively stable synthetic fluid composition|
    US5174913A|1991-09-20|1992-12-29|Westvaco Corporation|Polybasic acid esters as oil field corrosion inhibitors|
    DE19546117A1|1995-12-11|1997-06-12|Henkel Kgaa|Non-toxic heat transfer oils|
    US6884761B2|2001-12-18|2005-04-26|Bp Corporation North America Inc.|High temperature stable lubricant mixed polyol ester composition containing an aromatic carboxylic acid and method for making the same|
    EP3556829B1|2016-12-13|2022-02-23|Kao Corporation|Lubricant base oil and lubricant composition including said lubricant base oil|
    JP2018095840A|2016-12-13|2018-06-21|花王株式会社|Lubricant base oil, and lubricant composition including the same|
    JP6928445B2|2016-12-21|2021-09-01|花王株式会社|Lubricating oil base oil, lubricating oil composition containing the lubricating oil base oil, and a method for producing the same.|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    IT25573/79A|IT1123575B|1979-09-10|1979-09-10|POLYVALENT ALCOHOL ESTERS, PROCEDURE FOR THEIR PREPARATION AND USE AS LUBRICANTS|
    IT2299280A|IT1132124B|1980-06-24|1980-06-24|Poly:ol ester derived from hexa:hydro-benzoic acid|
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